1,3‐(C → O) Silyl Shift in α‐Diazo α‐Silyl Ketones: Cycloaddition Reactions and Kinetic Proof for the β‐Siloxydiazoalkene Intermediate
- 1 March 1991
- journal article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 30 (3) , 306-308
- https://doi.org/10.1002/anie.199103061
Abstract
No abstract availableKeywords
This publication has 21 references indexed in Scilit:
- Difluoropropadienone as a source of difluorovinylidene and difluorodiazoetheneJournal of the American Chemical Society, 1990
- An ab initio study of diazoethene, a propadienone isoelectronic with a bent structureJournal of the American Chemical Society, 1988
- Synthesis and reactivity of diazomethylenephosphoranes (P=C=N2). New phosphacumulene ylides and first stable pseudo-unsaturated diazo derivativesJournal of the American Chemical Society, 1987
- Thermal Decomposition of α‐Diazo‐α‐(trialkylsilyl)alkanones – Intramolecular C/H Insertion of Siloxyalkylidenecarbene IntermediatesEuropean Journal of Inorganic Chemistry, 1987
- Preparation of 1-aryl-2-siloxyalkynes from silylated .alpha.-diazocarbonyl compoundsThe Journal of Organic Chemistry, 1985
- Thermal rearrangement of an allenic diazoalkane and intermolecular capture of a diazoethene by a cyclopropene to give a common dihydropyridazine productJournal of the American Chemical Society, 1981
- Zum kinetischen Nachweis reaktiver ZwischenstufenAngewandte Chemie, 1970
- Kinetic Evidence for Reactive IntermediatesAngewandte Chemie International Edition in English, 1970
- Metallsubstituierte Carbene und C‐metallierte Diazoalkane, III1) Trimethylsilyl‐diazoessigsäureäthylester und seine Photolyse zum Trimethylsilyl‐äthoxycarbonylcarbenEuropean Journal of Organic Chemistry, 1969
- Zur Valenztautomerie des CyclooctatetraensAngewandte Chemie, 1964