Cyclopalladated imine catalysts in Heck arylation: search for the catalytic species
- 18 September 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 19,p. 1877-1878
- https://doi.org/10.1039/b004502k
Abstract
The application of the new cyclopalladated imine complexes of the Milstein-type 1d, 2a and 2b and the immobilised derivative 2c in the Heck reaction has provided evidence that these complexes are unstable and the active species is metallic palladium.Keywords
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