Stereospecific synthesis of chiral N-(ethynyl)allylglycines and their use in highly stereoselective intramolecular Pauson–Khand reactions
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 1879-1880
- https://doi.org/10.1039/a905898b
Abstract
The first synthesis of an enantiopure N-ethynylated allylglycine and its application in the intramolecular Pauson–Khand reaction, which leads to a novel highly functionalised proline derivative with complete control of stereoselectivity, is reported.Keywords
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