Conversion of distorted tetrahedral bis(benzyldiphenylphosphine)dibromonickel(II) into a pure planar complex by high pressure
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 266-267
- https://doi.org/10.1039/c39730000266
Abstract
Electronic and far-i.r. spectral evidence for a structural change occurring in the solid state between the distorted tetrahedral and planar forms of Ni(Ph2PCH2-Ph)2Br2, produced by high external pressure, has been obtained; this is the first reported spin-pairing occurring for solid nickel complexes, and conversion from a distorted tetrahedral into a planar structure with an increase in pressure.Keywords
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