Nitroamine radicals as intermediates in the functionalization of non-activated carbon atoms
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 958-959
- https://doi.org/10.1039/c39800000958
Abstract
Photolysis of N-iodonitroamines generated in situ from the steroidal nitroamines 6β-nitroamino-5α-cholestan-3β-ol acetate, 6β-nitroamino-5α-cholestane-3β,5α-diol diacetate, and 20R-nitroaminopregn-5-en-3-ol acetate removes hydrogen atoms from the Me-18 and Me-19 groups to give 6β-,19-N-nitroepinino-5α-cholestan-3β-ol acetate, 6β,19-N-nitroepinino-5α-cholestane-3β5α-diol diacetate, and 18,20R-N-nitroepiminopregn-5-en-3β-ol acetate.Keywords
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