Magnetic exchange and anisotropic susceptibilities in high-spin binuclear cobalt II species
- 21 March 1978
- journal article
- Published by The Royal Society in Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- Vol. 360 (1701) , 161-189
- https://doi.org/10.1098/rspa.1978.0062
Abstract
A model is described for the calculation of the principal magnetic susceptibilities of exchange-coupled binuclear cobaltn species. The two-centre exchange calculation is performed within a basis constructed from appropriately antisymmetrized products of the one-centre functions belonging to the 4F + 4P terms. The exchange parameters refer to interactions between separate one-centre orbitals, in the spirit of Anderson’s kinetic and potential exchange pathways, so bearing some resemblance to the angular overlap parameters used to describe the one-centre, ligand-field perturbation.Keywords
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