The First Molecular Superconductor Based on π-Acceptor Molecules and Closed-Shell Cations, [(CH3)4N][Ni(dmit)2]2, Low-Temperature X-Ray Studies and Superconducting Transition
- 5 September 1987
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 16 (9) , 1819-1822
- https://doi.org/10.1246/cl.1987.1819
Abstract
Low-temperature structural study of [(CH3)4N][Ni(dmit)2]2 suggested that the rotational freedom of methyl group seems to play an important role in the “metal-semimetal” transition. Superconducting transition was observed at 5 K (7 kbar).Keywords
This publication has 2 references indexed in Scilit:
- Molecular designing analysis of a new superconducting metal dithiolene complexSolid State Communications, 1987
- Organic Superconductors: A Survey of Low Dimensional PhenomenaMolecular Crystals and Liquid Crystals, 1982