Notizen: Pyridin-2-thiolato-komplexe des Kupfer(I) und Kobalt(III) / Pyridine-2-thiolato Complexes of Copper(I) and Cobalt(III)
Open Access
- 1 April 1975
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 30 (3-4) , 284-285
- https://doi.org/10.1515/znb-1975-3-433
Abstract
Pyridine-2-thiolato complexes of copper(I) and cobalt (III) have been prepared from copper(II)- and cobalt(III)-acetylacetonate with pyridine-2-thiol as well as by reacting CuCl(pyridine-2-thiol)3 and CoCl2-(pyridine-2-thiol)2 with a base. The copper(I) complex forms an addition product of low stability with triphenylphosphine. The cobalt complex is monomeric whereas according to its mass spectrum pyridine-2-thiolato-copper(I) appears to be tetrameric.Keywords
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