HIGHLY ACTIVE POLYMER-SUPPORTED Pd COMPLEX. A NEW SYNTHETIC METHOD AND ITS USE IN SELECTIVE HYDROGENATION OF OLEFINS AND ACETYLENES
- 5 October 1975
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 4 (10) , 1005-1008
- https://doi.org/10.1246/cl.1975.1005
Abstract
The palladium chloride complex supported on polymeric diphenylbenzyl phosphine is very active for both hydrogenation of olefins and acetylenes, and isomerization of double bonds. This high activity is probably due to the formation of the coordinatively unsaturated palladium.This publication has 3 references indexed in Scilit:
- Catalytic reactions using polymer-bound vs. homogeneous complexes of nickel, rhodium, and rutheniumJournal of the American Chemical Society, 1975
- Heterogeneous selective catalysis of the hydrogenation of olefins by polymeric palladium(II) and platinum(II) complexesInorganic Chemistry, 1973
- Homogeneous catalysis in the reactions of olefinic substances. IX. Homogeneous catalysis of specific hydrogenation of polyolefins by some platinum and palladium complexesJournal of the American Chemical Society, 1967