The reactions of hydrogen atoms with solids at low temperature. Part I. Apparatus, hydrocarbon, and hydrogen cyanide reactions
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2474-2478
- https://doi.org/10.1039/j19710002474
Abstract
A novel apparatus is described for the production of a high density stream of hydrogen atoms and the investigation of the reactions of these atoms with solids at low temperature by i.r. spectroscopy. A critical analysis of the technique is made and its application to the study of the reactions of hydrogen atoms with hydrocarbons and hydrogen cyanide is described. A new reaction with trans-but-2-ene is described. Solid hydrogen cyanide reacts at low temperatures with hydrogen atoms to form an intermediate which may be CH2 NH.Keywords
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