Free radical reactions in solution. Part 7. Substituent effects on free radical reactions: comparison of the σ˙ scale with other measures of radical stabilization
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 8,p. 1127-1131
- https://doi.org/10.1039/p29810001127
Abstract
The σ˙ scale of radical stabilization derived from the thermal decomposition of substituted dibenzyl mercurials is compared with other proposed scales. By using the σ˙ scale, the parameter ρ˙ can be used as a probe for the amount of radical character developed or destroyed in the transition state of a free radical reaction.Keywords
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