Electrochemical reduction of carbon dioxide catalysed by macrocyclic Fe4S4iron–sulphur clusters
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 194-195
- https://doi.org/10.1039/c39900000194
Abstract
Electrochemical fixation of CO2 into formate was efficiently carried out by using Fe4S4 cubane clusters bearing a 36-membered methylene backbone in dimethylformamide with initial current efficiencies of 40 and 23%, respectively, for t-butyl and benzyl type macrocyclic Fe–S derivatives; these derivatives are several times more efficient than conventional clusters bearing small thiolate ligands.Keywords
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