Asymmetric synthesis of indolizidine alkaloids by ring-closing–ring-opening metathesis
- 19 July 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 16,p. 1501-1502
- https://doi.org/10.1039/b004106h
Abstract
Asymmetric Pd(0) catalyzed allylic amination followed by a Ru catalyzed RCM–ROM sequence converted an easily accessible racemic cyclopentenol 2 to the functionalized tetrahydropyridine 9 which can be used for the asymmetrical synthesis of indolizidine 13.Keywords
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