Fermi contact nuclear magnetic resonance shifts in glyme complexes of the coronene radical anion-pair
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 16,p. 1035-1036
- https://doi.org/10.1039/c29700001035
Abstract
1 H n.m.r. spectra of glyme molecules complexed to sodium coronene radical ion-pairs show downfield shifts of 6 to 10 p.p.m. due to a Fermi contact interaction between the glyme protons and the unpaired electron, and the observed detail in the n.m.r. pattern suggests a rather well-defined structure of the ion-pair complex in solution.Keywords
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