Ground State of the Kagomé-Like S=1/2 Antiferromagnet Volborthite Cu3V2O7(OH)2·2H2O

Abstract
The volborthite compound is one of the very few realizations of S=1/2 quantum spins on a highly frustrated kagomé-like lattice. Low-T SQUID measurements reveal a broad magnetic transition below 2 K which is further confirmed by a peak in the V51 nuclear spin relaxation rate (1/T1) at 1.4K±0.2K. Through V51 NMR, the ground state (GS) appears to be a mixture of different spin configurations, among which 20% corresponds to a well defined short-range order, possibly of the 3×3 type. While the freezing involves all the Cu2+ spins, only 40% of the copper moment is actually frozen which suggests that quantum fluctuations strongly renormalize the GS.
All Related Versions