Far-Infrared Spectra of Mercuric Halides and Their Dioxane Complexes
- 15 December 1966
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 45 (12) , 4528-4535
- https://doi.org/10.1063/1.1727533
Abstract
The far‐infrared spectra (600–60 cm−1) of HgCl2, HgBr2, HgI2 (red), and their one‐to‐one p‐dioxane complexes (in the solid state) were investigated. All of the observed spectra, except those of HgI2, were assigned on the base of the symmetry properties of the crystals. High‐pressure effects were investigated for the anti‐symmetric stretching vibration of HgCl2 and its dioxane complex. The frequency shifts of all of the compounds in the various states, from the gaseous state through the dioxane complex under high pressure, were elucidated in terms of the distance between the mercury atom and its nearest neighbors.Keywords
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