Phase-Transfer Catalytic Alkylation of Hydroperoxides: A Convenient Route to Mixed Dialkyl Peroxides
- 1 February 1990
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 20 (3) , 349-353
- https://doi.org/10.1080/00397919008052775
Abstract
The solid-liquid phase transfer catalytic alkylation of hydroperoxides using solid potassium hydroxide as a base and TEBAC as a phase transfer catalyst is reported. When the alkylating agent is a primary bromide, this reaction represents a simple and quick method for the synthesis of mixed dialkyl peroxides in fair yields.Keywords
This publication has 5 references indexed in Scilit:
- Intramolecular homolytic displacements 7 — Free radical additions to unsaturated peroxy compounds : Synthesis of oxygenated heterocyclesTetrahedron, 1985
- A synthesis of mixed dialkylperoxides via reaction of an alkylhydroperoxide with alkyl trifluoromethane sulfonatesThe Journal of Organic Chemistry, 1976
- A convenient and general preparation of alkyl hydroperoxides and dialkyl peroxidesJournal of the Chemical Society, Chemical Communications, 1976
- Preparation and Properties of Some Allylic PeroxidesJournal of the American Chemical Society, 1951
- THE BASE CATALYZED DECOMPOSITION OF A DIALKYL PEROXIDEJournal of the American Chemical Society, 1951