A cis-dioxoruthenium(VI) complex as active oxidant of chloride and organic substrates; preparation, characterization, and reactivity of cis-[RuVI(6,6′-Cl2bpy)2O2]2+(6,6′-Cl2bpy = 6,6′-dichloro-2,2′-bipyridine)
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1376-1377
- https://doi.org/10.1039/c39870001376
Abstract
Oxidation of cis-[RuII(6,6′-Cl2bpy)2(OH2)2]2+ with CeIV gave cis-[RuVI(6,6′-Cl2bpy)2O2]2+, isolated as the diamagnetic ClO4 – salt, which rapidly oxidizes Cl–(to Cl2) and a wide variety of organic substrates (tetrahydrofuran to butyrolactone and cyclohexane to cyclohexanone).Keywords
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