? and ? Organometallic derivatives of titanium(III) and vanadium(III) bonded to a dibenzotetramethyletetra-aza[14]annulene ligand
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1401-1403
- https://doi.org/10.1039/c39860001401
Abstract
Reaction of MCl3(thf)3(thf = tetrahydrofuran; M = Ti or V) with Li2(tmtaa = 7,16-dihydro-6,8,16,17-tetramethyldibenzo[b,i][1,4,8,11]tetra-azacyclotetradecinato dianion) led to [M(tmtaa)(Cl)] complexes, which can be transformed into the corresponding organometallic derivatives [(tmtaa)V(mes)](mes = mesityl) and [(tmtaa)M(η5-C5H5)](M = V or Ti), whose structure was proven by X-ray analysis.Keywords
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