Selective formation of acrylonitrile via oxidative methylation of acetonitrile with methane over superbasic catalysts
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1290-1292
- https://doi.org/10.1039/c39930001290
Abstract
Promotion of CaO or MgO with various binary alkali metal compounds such as NaA + CsA, KA + CsA, LiA + CsA or LiA + NaA, where A = SO4 2–, OH–, Cl–, AcO–, CO3 2– or NO3 –, leads to highly basic (superbasic) catalysts, which exhibit a noticeable synergistic effect compared with the effect produced by any monoalkali promoted system in the selective formation of acrylonitrile viaoxidative methylation of acetonitrile with methane.Keywords
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