Crystal and Electronic Structures of a New Two-dimensional Molecular Metal, α-Et2Me2N[Ni(dmit)2]2
- 5 May 1988
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 17 (5) , 865-868
- https://doi.org/10.1246/cl.1988.865
Abstract
The anion radical salt α-Et2Me2N[Ni(dmit)2]2 retains metallic behavior down to 1.5 K. Planar Ni(dmit)2 units lying side-by-side along the b axis stack along the c axis in such a way that one molecule overlaps with two molecules. Such a “spanning overlap” mode has provided two-dimensional electronic structure.Keywords
This publication has 2 references indexed in Scilit:
- Molecular designing analysis of a new superconducting metal dithiolene complexSolid State Communications, 1987
- Highly conducting charge-transfer compounds of tetrathiafulvalene and transition metal-"dmit" complexesJournal of the American Chemical Society, 1986