Nuclear magnetic resonance evidence for the formation of cis- and trans-σ-but-2-enyl and syn-π-(1-methylallyl) complexes in the hydrogenation of butadiene by pentacyanocobaltate(II)
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 19,p. 1177-1178
- https://doi.org/10.1039/c29710001177
Abstract
Formation of similar amounts of cis- and trans-σ-but-2-enyl pentacyanocobaltate(III) and of syn-π-(1-methylallyl)tetracyanocobaltate(III) in the hydrogenation of butadiene by pentacyanocobaltate(II) is demonstrated from the i.r. spectrum and the n.m.r. spectra at 60, 100, and 220 MHz.Keywords
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