Arrhenius parameters for the reaction of propyl radicals with propane
- 15 September 1969
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 47 (18) , 3305-3311
- https://doi.org/10.1139/v69-550
Abstract
The reaction of n-propyl radicals from the photolysis of azo-n-propane with propane has been studied and Arrhenius parameters for hydrogen atom abstraction relative to the recombination of n-propyl radicals determined. From the Arrhenius parameters obtained and the available thermodynamic data, the Arrhenius parameters of the reverse reaction, the hydrogen atom abstraction from propane by iso-propyl radicals, have been calculated.Some complicating factors in the photolysis of azopropane are discussed.Keywords
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