Reactions of carbene with 1,1-dicyclopropylethylene. A new tool to investigate radical cycloadditions
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 389-390
- https://doi.org/10.1039/c39720000389
Abstract
Fluorenylidene reacts with 1,1-dicyclopropylethylene to give a cycloadduct (5) and the rearranged adduct (6) in a ratio of 10:1; dilution with decalin inverses the ratio to 1:3, which may be due to the increased amount of triplet fluorenylidene.Keywords
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