Halides and oxide halides of technetium. I. Technetium(V) oxide halides and the reaction of thionyl chloride with ammonium pertechnetate
- 1 January 1968
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 21 (8) , 1981-1985
- https://doi.org/10.1071/ch9681981
Abstract
Chlorination of technetium dioxide has been shown to give technetium oxide trichloride as the major product. The presence of an unstable second product, thought to be the oxide tetrachloride, was confirmed. Bromination of technetium dioxide gives only technetium oxide tribromide. Thionyl chloride reacts with ammonium pertechnetate to give ammonium dioxotetrachlorotechnetate(V1), which was isolated as its sulphuryl chloride adduct, (NH4),[TcO2Cl4],SO2Cl2.Keywords
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