Polymer-bound ligands and metal complexes via catalysed reactions of polybutadienes
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1767-1769
- https://doi.org/10.1039/c39910001767
Abstract
Polybutadiene functionalised with chlorosilyl groups via homogeneous catalytic reactions can be treated with picolyl- or bipyridyl-lithium reagents to give polymer-bound ligands, which will bind metal centres chemically or electrochemically; alternatively, zinc porphyrin units can be bound to the polymer via phenolysis of the Si–Cl bonds.Keywords
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