Aryltriazenido-complexes. Crystal and molecular structure of trans-carbonyl(1,3-di-p-tolyltriazenido)bis(triphenylphosphine)iridium(I)
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 7,p. 1098-1100
- https://doi.org/10.1039/dt9800001098
Abstract
The structure of the title compound has been determined by counter data. In this square-planar iridium complex the triazenido-ligand is unidentate and trans to the carbonyl group. The Ir–N(1) distance is 2.16(1) and the Ir–C(26)(carbonyl) 1.79(1)Å. The complex crystallizes in the monoclinic system, space group C2/c, with unit-cell dimensions a= 22.121(3), b= 19.190(3), c= 10.111(2)Å, and β= 92.77(5)°. The structure is refined to a conventional R index of 0.032.Keywords
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