Scaling properties of diffusion-limited reactions
- 1 August 1990
- journal article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 42 (4) , 2279-2283
- https://doi.org/10.1103/physreva.42.2279
Abstract
A simple scaling argument for diffusion-limited reactions for both A+A→0 and A+B→0 is developed. Temporally asymptotic behavior of species densities in the absence of sources and reaction orders in the steady state in the presence of sources are discussed. We specifically address the effect of the spatial distributions of reactants on the reaction rates. For the A+A→0 reaction we recover existing results found by other methods. For A+B→0 in the absence of sources we find that the asymptotic behavior depends not only on the spectral dimension (as commonly believed) but also on the fractal dimension. In the presence of sources we agree with previous results when the steady-state density is not too low, but argue that a modification of these results may occur at very low densities.Keywords
This publication has 15 references indexed in Scilit:
- Source-term and excluded-volume effects on the diffusion-controlled A+B→0 reaction in one dimension: Rate laws and particle distributionsPhysical Review A, 1989
- Steady-state diffusion-controlled A+A→0 reaction in Euclidean and fractal dimensions: Rate laws and particle self-orderingPhysical Review A, 1989
- Steady-state diffusion-controlled A+B→0 reactions in two and three dimensions: Rate laws and particle distributionsPhysical Review A, 1989
- Kinetics of bimolecular reactions in condensed media: critical phenomena and microscopic self-organisationReports on Progress in Physics, 1988
- Fractal Reaction KineticsScience, 1988
- Time resolved studies of naphthalene mixed crystals. Fractal and Euclidian behaviors of the migration kineticsThe Journal of Chemical Physics, 1984
- Scaling Approach for the Kinetics of Recombination ProcessesPhysical Review Letters, 1984
- Fractal reaction kinetics: exciton fusion on clustersThe Journal of Physical Chemistry, 1983
- Particle–antiparticle annihilation in diffusive motionThe Journal of Chemical Physics, 1983
- Role of density fluctuations in bimolecular reaction kineticsChemical Physics, 1978