Inclusion compounds of binaphthol with volatile guests: structures, selectivity and kinetics of desolvation

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Abstract
Binaphthol forms inclusion compounds with 1,4-dioxane, morpholine, dimethylsulfoxide, acetone and tetrahydrofuran. The host∶guest ratios of some of these compounds depend on the crystallisation temperature. Competition experiments between pairs of selected guests reveal different kinds of selectivity. Desolvation kinetics for these compounds yield similar activation energies of approximately 80 kJ mol−1.
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