On the electron spin resonance detection of RS radicals in irradiated solids: radicals of type RSSR–, RS–SR2, and R2SSR2+
- 1 January 1974
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 13,p. 1618-1620
- https://doi.org/10.1039/p29740001618
Abstract
It is suggested that radicals previously identified as RS, having g tensor components in the 2·002, 2·025, and 2·060 regions are better described as RS–SR2σ* radicals, structurally similar to the established radical anions, RS–SR–. Furthermore, a radical in irradiated thiodiglycolic acid previously thought to be (HO2CCH2)2S+ is almost certainly the dimer-cation (HO2CCH2)2S–S(CH2CO2H 2)+. The type of spectrum expected for RS radicals including HS is discussed, together with possible assignments.Keywords
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