The reactions of [FeH(H2)(Me2PCH2CH2PMe2)2][BPh4] with allenes and acetylenes, and the reduction of cyclopropane by molybdenum nitrogenases
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 522-524
- https://doi.org/10.1039/c39910000522
Abstract
The reduction of cyclopropenes by metal hydrides shows significant parallels with their reduction by Klebsiella pneumoniae nitrogenase; intermediates isolated from the reduction of the isomeric allenes and acetylenes by [FeH(H2)(Me2PCH2CH2PMe2)2][BPh4] show novel features of much wider implication.Keywords
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