Resolution of coupled electron transfer–ion transfer processes at liquid/liquid interfaces by visualisation of interfacial concentration profiles

1 January 1999

journal article
research article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 16,p. 1501-1502
https://doi.org/10.1039/a904641k

Abstract

A powerful approach for investigating heterogeneous electron transfer (ET) reactions at liquid/liquid (oil/water) interfaces is described and illustrated with studies of the reactions between IrCl₆ ^2– or Fe(CN)₆ ^3– in an aqueous phase and decamethylferrocene (DMFc) or ferrocene (Fc) in 1,2-dichloroethane (DCE).

Keywords

COUPLED ELECTRON
LIQUID/LIQUID INTERFACES
CONCENTRATION PROFILES
AQUEOUS PHASE
INTERFACIAL CONCENTRATION
POWERFUL APPROACH
INVESTIGATING HETEROGENEOUS
TRANSFER PROCESSES
ION TRANSFER
HETEROGENEOUS ELECTRON

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