Pulsed laser photolysis of chlorocopper(II) complexes in acetonitrile: evidence for chlororadical formation
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 207-208
- https://doi.org/10.1039/c39780000207
Abstract
Nd pulsed laser excitation at 473 nm of the system CuCl2–LiCl-acetonitrile, where CuCl4 2– predominates in the equilibrium mixture, leads to formation of a transient which corresponds to the Cl2 – radical anion and is not scavenged by the solvent.Keywords
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