Rotational Isomerism and the Vibrational Spectrum of Sym-Dideuterodibromoethane
- 1 August 1952
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 20 (8) , 1227-1231
- https://doi.org/10.1063/1.1700716
Abstract
Trans‐ethylene‐d2 was brominated by two methods, which involved different stereochemical paths, to give 95 percent meso‐BrDHC‐CHDBr as one product and a mixture of meso‐ and racemic‐BrDHC‐CHDBr as the other. Liquid phase Raman spectra and liquid and solid phase infrared spectra of these materials have been obtained and a tentative assignment of the vibrational frequencies of BrDHC‐CHDBr to the trans and skew configurations of the meso and racemic compounds has been made.Keywords
This publication has 8 references indexed in Scilit:
- Rotational Isomerism and the Vibrational Spectrum of 1,2-DibromoethaneThe Journal of Chemical Physics, 1950
- Rotational Isomerism in Substituted Ethanes Possessing Asymmetric Carbon AtomsThe Journal of Chemical Physics, 1950
- The Vibrational Spectra of Molecules and Complex Ions in Crystals III. Ammonium Chloride and Deutero-Ammonium ChlorideThe Journal of Chemical Physics, 1950
- Kinetics of thermal addition of halogens to olefinic compoundsQuarterly Reviews, Chemical Society, 1949
- The Role of Neighboring Groups in Replacement Reactions. VIII. The Reaction of Stilbene Dichlorides with Silver AcetateJournal of the American Chemical Society, 1946
- Raman spectra and molecular configurations of solid ethylene dihalidesProceedings of the Indian Academy of Sciences - Section A, 1938
- THE SYNTHESIS OF TETRADEUTEROHOMOCYSTINE AND DIDEUTEROMETHIONINEPublished by Elsevier ,1938
- The Halogenation of EthylenesJournal of the American Chemical Society, 1937