An unusual rearrangement observed in the mass spectra of several 1‐alkyl‐2‐substituted‐5‐nitroimidazoles
- 1 October 1972
- journal article
- Published by Wiley in Journal of Mass Spectrometry
- Vol. 6 (10) , 1117-1119
- https://doi.org/10.1002/oms.1210061008
Abstract
The mass spectra of several l‐alkyl‐2‐substituted‐5‐nitro imidazoles exhibit prominent rearrangement ions corresponding to the loss of CnH2nO from the molecular ion. The effect on this rearrangement upon variation of the group at position 2 is discussed.Keywords
This publication has 9 references indexed in Scilit:
- Ortho effects–I: Fragmentation mechanisms in some ortho‐substituted nitroarenesJournal of Mass Spectrometry, 1970
- Mass spectrometryAnalytical Chemistry, 1970
- Bond formation upon electron—impactJournal of Mass Spectrometry, 1969
- 2-Amino-5-(1-methyl-5-nitro-2-imidazolyl)-1,3,4-thiadiazole: A New Antimicrobial AgentScience, 1968
- Photochemical analogies in mass spectra. An ortho effect.Tetrahedron Letters, 1968
- Electron‐Impact Induced Rearrangement Reactions of Organic MoleculesAngewandte Chemie International Edition in English, 1967
- Organic Ions in the Gas Phase. XVIII. Mass Spectra of NitroarenesJournal of the American Chemical Society, 1966
- 1187. The dissociation of O -nitrotoluene under electron impactJournal of the Chemical Society, 1965
- The determination of carbon skeleton of sarpagine by mass spectrometryTetrahedron Letters, 1960