Preparation and X-ray crystallographic characterisation of an unusual heteronuclear complex, RhAg2(CCC6F5)5(PPh3)3
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 688-689
- https://doi.org/10.1039/c39740000688
Abstract
The complex RhAg2(CCC6F5)5(PPh3)3, prepared from RhCl(PPh3)3 and Ag(CCC6F5), contains a central rhodium atom which is octahedrally co-ordinated to one PPh3 ligand and five σ-acetylide units; each PPh3Ag group is π-bonded to three acetylenic bonds (one acetylenic linkage thereby being involved with both silver atoms); rhodium–silver distances are 3.086(1) and 3.102(1)Å.Keywords
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