Biosynthesis of the polyketide mellein from CD3CO2H and 13CD3CO2H in Aspergillus melleus: detection of deuterium by 2H n.m.r. and edited 13C n.m.r. spectra
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 694-696
- https://doi.org/10.1039/c39830000694
Abstract
The pattern of incorporation of deuterium into mellein from CD3CO2H and 13CD3CO2H was investigated by 2H n.m.r. and edited 13C n.m.r. spectra; the deuterium incorporated into the C-4 methylene group was found to be evenly distributed between the two diastereoisotopic positions and molecules were detected which retained two deuteriums at that site.Keywords
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