Detailed Dynamic NMR Study of a Molecular Gear, 1-Methoxy-9-(3,5-dimethylbenzyl)triptycene
- 1 December 1989
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 62 (12) , 4058-4060
- https://doi.org/10.1246/bcsj.62.4058
Abstract
Stereodynamics of the title compound was studied by dynamic NMR spectroscopy. The “isolated” rotation of the aryl group was found to have a lower barrier than the correlated gear rotation.Keywords
This publication has 4 references indexed in Scilit:
- Restricted Rotation Involving the Tetrahedral Carbon. LIX. Stereodynamics of Singly peri-Substituted 9-(3,5-Dimethylphenoxy)triptycene DerivativesBulletin of the Chemical Society of Japan, 1986
- Restricted Rotation Involving the Tetrahedral Carbon. LVII. Stereodynamics of 9-(2-Alkylphenoxy)-1,4-dimethyltriptycenesBulletin of the Chemical Society of Japan, 1985
- Molecular gears with two-toothed and three-toothed wheelsJournal of Molecular Structure, 1985
- Restricted Rotation Involving the Tetrahedral Carbon. XXXV. Stereodynamics of 9-(3,5-Dimethylbenzyl)triptycene DerivativesBulletin of the Chemical Society of Japan, 1981