Negative ion mass spectra of organometallic compounds; electron capture-induced decarbonylation of an ester group in a π-arene metal carbonyl
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1004-1005
- https://doi.org/10.1039/c39740001004
Abstract
Secondary electron capture by (π-methyl benzoate)tricarbonylchromium yields a molecular anion which undergoes decarbonylation and further loss of three CO groups; in addition, Cr– ions have been identified in the 70 eV negative ion mass spectrum of this compound.Keywords
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