Photoisomerisation of ion pairs of diphenylallyl carbanions
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 3,p. 249-253
- https://doi.org/10.1039/p29780000249
Abstract
The normal trans,trans conformation of the ion pairs of the 1,3-diphenylallyl and 1,3-diphenylbutenyl carbanions is converted into cis,trans by photolysis with white light. The kinetics of the reverse dark reaction have been studied; the rate of this process is much greater for the tight than for the loose ion pair.Keywords
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