STEREOSELECTIVE TOTAL SYNTHESES OF (±)- AND OPTICALLY ACTIVE DEHYDROIRIDODIOLS
- 5 January 1983
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 12 (1) , 147-148
- https://doi.org/10.1246/cl.1983.147
Abstract
(±)-Dehydroiridodiol and its epimer (±)-isodehydroiridodiol were synthesized stereoselectively using the homoconjugate addition of cyanide anion to methyl 6-methyl-2-oxobicyclo[3.1.0]hexane-1-carboxylates. Both enantiomers of dehydroiridodiol were prepared after the resolution of l-menthyl 6-methyl-2-oxobicyclo[3.1.0]hexane-1-carboxylate, whose absolute configurations became clear as the result.This publication has 6 references indexed in Scilit:
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