Thermal isomerisation of methyl linoleate hydroperoxides. Evidence of molecular oxygen as a leaving group in a radical rearrangement
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 756-757
- https://doi.org/10.1039/c39780000756
Abstract
Using an 18O-enriched hydroperoxide, the pentadienyl hydroperoxides (1–4) were shown to undergo rearrangement in which the oxygen atoms of the hydroperoxy group exchanged with atmospheric oxygen.Keywords
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