Electron spin resonance studies. Part XXXVI. Formation of ion-pairs by semidiones and related radicals in aqueous solution
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 14,p. 2053-2056
- https://doi.org/10.1039/p29720002053
Abstract
The one-electron oxidation of some α-hydroxy-acids or the one-electron reduction of α-keto-acids or α-diketones, in aqueous solution, yields hydroxysemidiones or semidiones which, in the presence of an appropriate di- or tripositive metal ion, give metal complexes; in some cases metal-ion splittings can be observed. Data relating to the structures of the complexes are reported and discussed.Keywords
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