Selective hydroformylation with a recoverable dirhodium µ-thiolato complex
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1056-1057
- https://doi.org/10.1039/c39890001056
Abstract
The dimeric precursor complex {Rh2[µ-S(CH2)3N(Me)2]2(Cod)2}, (cod = cyclo-octa-1,5-diene), with PPh3 catalyses the hydroformylation of hex-1-ene, under mild conditions, into heptanals with high yields and selectivities; owing to the presence of the amine group the rhodium catalyst can be quantitatively recovered from the reaction mixture by adding dilute H2SO4, and reused without loss of activity.Keywords
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