Darstellung, Kristallstruktur und Schwingungsspektren von cyclo-Undekaschwefel (S₁₁) und von cyclo-Tridekaschwefel (S₁₃) / Preparation, Crystal Structure, and Vibrational Spectra of cyclo-Undecasulfur (S₁₁) and of cyclo-Tridecasulfur (S₁₃)

Open Access

1 August 1986

journal article
Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B

Vol. 41 (8) , 958-970
https://doi.org/10.1515/znb-1986-0806

Abstract

The homocyclic S₁₁ and S₁₃ molecules have been synthesized from titanocenepentasulfide and S₆Cl₂ or S₈Cl₂, respectively, and obtained as yellow crystals which are metastable for several days at 20 °C. X-Ray structural analyses of single crystals at -105± 5 °C exhibited molecules of approximately C₂ symmetry with bond distances (d), bond angles (a) and torsional angles (r) in the following ranges: S₁₁ : d = 203.2 -211.0 pm, α = 103.3-108.6°, τ = 69.3 - 140.5°; S₁₃: d = 197.8 - 211.3 pm, α = 102.8-111.1°, τ = 29.5 - 116.3°. Infrared and Raman spectra of S₁₁ and S₁₃ are reported. In addition, the synthesis of S₆Cl₂ and S₈Cl₂ from S₆ or S₈, respectively, and chlorine is described.

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Darstellung, Kristallstruktur und Schwingungsspektren von cyclo-Undekaschwefel (S11) und von cyclo-Tridekaschwefel (S13) / Preparation, Crystal Structure, and Vibrational Spectra of cyclo-Undecasulfur (S11) and of cyclo-Tridecasulfur (S13)

Abstract

Keywords

Darstellung, Kristallstruktur und Schwingungsspektren von cyclo-Undekaschwefel (S₁₁) und von cyclo-Tridekaschwefel (S₁₃) / Preparation, Crystal Structure, and Vibrational Spectra of cyclo-Undecasulfur (S₁₁) and of cyclo-Tridecasulfur (S₁₃)