Frequency and intensity patterns of LAM progression in weakly coupled chains: The case of stearic acid and stearyl alcohol
- 1 December 1984
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 81 (11) , 4782-4789
- https://doi.org/10.1063/1.447503
Abstract
The coupled oscillatormodel previously described for the interpretation of longitudinal acoustical modes (LAM) of weakly coupled chain molecules has been extended in order to account for the observed frequency and intensity patterns in stearic acid and stearyl alcohol. The model and its general validity are discussed and a specific comparison is made with data obtained from Raman measurements on hexatriacontane (n‐C3 6H7 4), stearic acid (n‐C1 7H3 5–COOH), and stearyl alcohol (n‐C1 8H3 7OH).Keywords
This publication has 10 references indexed in Scilit:
- Accordian‐type Laser‐Raman scattering by polymersJournal of Polymer Science: Polymer Physics Edition, 1982
- End effects on longitudinal accordion modes: fatty acids and layered systemsThe Journal of Physical Chemistry, 1982
- Hydrogen bonding effects on the skeletal optical and the longitudinal acoustical modes in long chain molecules and polymersJournal of Polymer Science: Polymer Physics Edition, 1979
- Longitudinal acoustic mode in polymers: Applications of the general theory to planar zigzag methylene chainsJournal of Applied Physics, 1977
- Longitudinal acoustic mode in polymers. II. Solution of the general composite perturbed elastic rodJournal of Polymer Science: Polymer Physics Edition, 1977
- Dynamical charge transfer through hydrogen bonds: Hartree–Fock calculations of vibrational properties of formic acid monomer and cyclic dimerThe Journal of Chemical Physics, 1977
- A raman spectroscopic determination of the interlamellar forces in crystalline n‐alkanes and of the limiting elastic modulus Ec of polyethyleneJournal of Polymer Science: Polymer Physics Edition, 1976
- On the problem of the vibrational spectrum and structure of ice Ih: Lattice dynamical calculationsThe Journal of Chemical Physics, 1973
- Lattice Dynamics of Methanol: Hydrogen Bonding and Infrared AbsorptionThe Journal of Chemical Physics, 1971
- Longitudinal Acoustical Vibrations of Finite Polymethylene ChainsThe Journal of Chemical Physics, 1967