Natural acetylenes. Part XXXVIII. Biosyntheses of acetylenedicarboxamide (cellocidin) in Streptomyces SF-536 cultures

Abstract
Biosynthetic experiments with a number of differently 14C-labelled hypothetical precursors have shown that cellocidin (acetylenedicarboxamide) is an offshoot of the Krebs cycle and arises in Streptomyces SF-536 cultures directly from carbon atoms 2–5 of 2-oxoglutarate.

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