Can the spin-delocalization effect express itself at the transition state of the hydrogen-atom abstraction reaction? Correlation analysis of relative rates measured by a rigorous methodology for eleven p-Y-substituted isopropylbenzenes
- 1 January 1994
- journal article
- Published by Elsevier in Tetrahedron
- Vol. 50 (25) , 7503-7512
- https://doi.org/10.1016/s0040-4020(01)90478-8
Abstract
No abstract availableKeywords
This publication has 35 references indexed in Scilit:
- The spin-delocalization substituent parameter σ·JJ. 9. Cyclodimerization rates of para-methylsulfinyl and para-methylsulfonyl α,β,β-trifluorostyrenesJournal of Fluorine Chemistry, 1994
- Single‐parameter versus dual‐parameter correlation for radical reactions. Addition of bromine atoms to α‐methylstyrenesJournal of Physical Organic Chemistry, 1994
- A self-consistent and cross-checked scale of spin-delocalization substituent constants, the .sigma.JJ.bul. scaleThe Journal of Organic Chemistry, 1992
- Negligible kinetic solvent interactions for the rate of photobromination of toluenes where the bromine atom is a principal chain carrierJournal of Physical Organic Chemistry, 1990
- The spin delocalization substitutent parameter ?JJ. 5. Correlation analysis of19F chemical shifts of substituted trifluorostyrenes. The unresolved polar substituent parameter ?mbJournal of Physical Organic Chemistry, 1990
- Positive halogen compounds. XVI. Comparison of alkoxy radicals from different sources and the role of halogen atoms in hypohalite reactionsJournal of the American Chemical Society, 1969
- THE INHIBITED AUTOXIDATION OF STYRENE: PART II. THE RELATIVE INHIBITING EFFICIENCIES OF META- AND PARA-SUBSTITUTED PHENOLSCanadian Journal of Chemistry, 1963
- The Mechanism of Benzylic Bromination with N-BromosuccinimideJournal of the American Chemical Society, 1963
- Relative Reactivities of Substituted Toluenes Toward Trichloromethyl RadicalsJournal of the American Chemical Society, 1960
- A Reëxamination of the Hammett Equation.Chemical Reviews, 1953