A NEW METHOD FOR DEOXYGENATION OF HETEROAROMATIC N-OXIDES WITH CHLOROTRIMETHYLSI LANE/SODIUM IODIDE/ZINC
- 5 July 1981
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 10 (7) , 921-924
- https://doi.org/10.1246/cl.1981.921
Abstract
Heteroaromatic N-oxides are easily deoxygenated with chlorotrimethylsilane/sodium iodide/zinc in acetonitrile to give the corresponding parent bases in good yields.This publication has 7 references indexed in Scilit:
- Dealkylation Reaction of Acetals, Phosphonate, and Phosphate Esters with Chlorotrimethylsilane/Metal Halide Reagent in Acetonitrile, and Its Application to the Synthesis of Phosphonic Acids and Vinyl PhosphatesBulletin of the Chemical Society of Japan, 1981
- Synthetic methods and reactions. 85. Reduction of .alpha.-halo ketones with sodium iodide/chlorotrimethylsilaneThe Journal of Organic Chemistry, 1980
- Synthetic methods and reactions. 62. Transformations with chlorotrimethylsilane/sodium iodide, a convenient in situ iodotrimethylsilane reagentThe Journal of Organic Chemistry, 1979
- The utility of hexachlorodisilane for the deoxygenation of nitrones, 2H-imidazole 1-oxides, 5H-pyrazole 1-oxides, and related N-hydroxy compoundsThe Journal of Organic Chemistry, 1978
- 3-Sulfolene as an alternative reagent for sulfur dioxide.CHEMICAL & PHARMACEUTICAL BULLETIN, 1978
- Deoxygenation of aryl nitro compounds with disilanesThe Journal of Organic Chemistry, 1975
- A New Oxygen-Insertion Reaction into Silicon-Silicon Bonds with Tertiary Amine OxidesBulletin of the Chemical Society of Japan, 1971