Insertion of norbornadiene into the aryl–palladium bond; synthesis, structure and dynamics of intramolecular η2-arene palladium species
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 710-712
- https://doi.org/10.1039/c39910000710
Abstract
A series of fluxional intramolecular η2-bound arene complexes, (C7H8Ar)Pdl(PPh3), 1a–1d, and 2 may be isolated from the catalytic reactions of norbornadiene (or norbornene) with aryl iodides in the presence of Zn and PdCl2(PPh3)2(eqn. 1) and their structures have been determined by X-ray crystallography and NMR spectroscopy.Keywords
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